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Multiwalled-carbon-nanotubes–preparation

Metal salts of carboxylic multiwalled carbon nanotubes – preparation, structure and thermal properties

physica status solidi (c). Special Issue: International Workshop on Nitride Semiconductors (IWN2010) • E-MRS – 2010 Fall Meeting – Symposium N • E-MRS – 2010 Fall Meeting – Symposium H. Volume 8, Issue 7-8, pages 2532–2537, July 2011

Abstract

Salts of carboxylated multiwalled carbon nanotubes with monovalent Ag(I), Li, Na, NH4, divalent Ba, Co(II), Cu(II), Pd(II), UO2, Zn, trivalent Ce(III), Cr(III), In(III), Ru(III), Sm(III), tetravalent Pt(IV), Th(IV) and pentavalent Nb(V) cations were prepared and elucidation of their structure was attempted based on their thermal and the QMS analyses. The salts usually decomposed specifically up to 400 °C. Above that temperature decomposition of the nanotubes matter can proceed with either oxidizing or catalyzing participation of the metal derivatives formed on the thermolysis of the metal salts.

Keywords:

    multiwalled carbon nanotubes;
    CNT carboxylates;
    thermolysis

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